Q.

Which of the following statements are correct?(i) ln octahedral complexes, dz2,dx2−y2 orbitals have higher energy than dxy,dyz and dzx orbitals.(ii) In tetrahedral complexes, dxy,dyz,dzx orbitals have higher energy than dz2 and dx2−y2 orbitals.(iii) The colours of complexes are due to electronic transitions from one set of d-orbitals to another set of orbitals.(iv) Δtetrahedral =94,Δoctahedral

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By Expert Faculty of Sri Chaitanya

a

(i), (ii) and (iii)

b

(i) and (iv)

c

(iii) and (iv)

d

(ii), (iii) and (iv)

answer is 1.

(Detailed Solution Below)

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Detailed Solution

Δtetrahedral =94,Δoctahedral
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