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a
Dipole moment:
b
Stability of free radical :
c
Basic strength: CH3O⊖> -OH>RS⊖
d
Basic and nucleophilic strength: I⊖>Br⊖>Cl⊖>F⊖
answer is A.
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Detailed Solution
(1) The smaller the angle, the larger the dipole moment, so μ of I> II > III.(2) (I) is 3° Allylic with conjugation.(II) is 3° Allylic.(III) 3° free radical. Hence, the order is I > II > III.(3) Acidity: RSH > CH3OH > H2OBasic strength: RS < CH3O ⊝< O⊝H(a) Acidity: HI > HBr > HCI > HFBasicity: I ⊝ < Br ⊝ < Cl ⊝ < F ⊝Nucleophilicity: I ⊝ > Br ⊝ > Cl ⊝ > F ⊝When nucleophilic centres are different and belong to the samegroup of periodic table, nucleophilicity is antiparallel to basicity.