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Q.

Which of the following statements is correct?

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a

Dipole moment:

b

Stability of free radical :

c

Basic strength: CH3O⊖> -OH>RS⊖

d

Basic and nucleophilic strength: I⊖>Br⊖>Cl⊖>F⊖

answer is A.

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Detailed Solution

(1) The smaller the angle, the larger the dipole moment, so μ of I> II > III.(2) (I) is 3° Allylic with conjugation.(II) is 3° Allylic.(III) 3° free radical. Hence, the order is I > II > III.(3) Acidity: RSH > CH3OH > H2OBasic strength: RS < CH3O   ⊝< O⊝H(a) Acidity: HI > HBr > HCI > HFBasicity: I   ⊝ < Br   ⊝ < Cl   ⊝ < F   ⊝Nucleophilicity: I   ⊝ > Br   ⊝ > Cl   ⊝ > F   ⊝When nucleophilic centres are different and belong to the samegroup of periodic table, nucleophilicity is antiparallel to basicity.
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