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Q.

Which of the following statements is correct for the FeH2O5NOSO4 complex?

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a

The EAN value of Fe in this complex depends on the charge of NO ligand.

b

The EAN value of Fe in this complex does not depend on the charge of NO ligand.

c

The hybridisation of the central atom is d2sp3

d

It is paramagnetic with μ=1.73BM

answer is B.

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Detailed Solution

FeH2O5(NO)2+ Hybridisation: sp3d2(n=3), μeff :3.89BMInspite of electronic transition from No to Fe2+, total number of electrons remain conserved.Hence EAN does not change.
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