Which of the following statements is correct regarding order of reaction
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a
first order reaction should be bimolecular
b
order of reaction must be positive
c
order depends upon stoichiometry
d
order is determined by experimental results
answer is D.
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Detailed Solution
1) Molecularity of first order reaction can be one, two (or) threeEx: Let us consider certain first order reactions. Elementary reactions are given asA → Products - I2A → Products - IIMolecularity in I is 'I' and II is '2'(2) order can be negative alsoEx: Conc. for a reactant increased by 2 times where rate becomes half 2x =2-1 (3) order is not the sum the coefficients of a stoichiometric equation.(4) It must be experimentally determined.