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Q.

Which of the following statements is incorrect ?

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a

The bond angle follows the order CH4 > NH3 > H2O > H2S

b

The bond order follows the order O2+> O2 >O2-> O22-

c

Strength of 'H' bond follows the order HF> H2O > NH3 > HCl

d

Of O-- C ≡ O+ , O = C = O , the structures,  O  +≡C - O-  is most stable structure

answer is D.

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Detailed Solution

I…. most stable …… All atoms possess octet and no charge separation.II, III …… Equally stable  but less stable than I because of charge separation (Both structures have octet on all atoms)(1) …. Correct …… CH4109.280   >   NH31070  >  H2O1050  >   H2S920 (2) …. Correct ……  O2+2.50   >   O22  >  O2−1.5  >   O2−21(3) …. Correct …… HF > H2O > NH3 > HClPolarity of H – F > H – O > H – N
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