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a
The bond angle follows the order CH4 > NH3 > H2O > H2S
b
The bond order follows the order O2+> O2 >O2-> O22-
c
Strength of 'H' bond follows the order HF> H2O > NH3 > HCl
d
Of O-- C ≡ O+ , O = C = O , the structures, O +≡C - O- is most stable structure
answer is D.
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Detailed Solution
I…. most stable …… All atoms possess octet and no charge separation.II, III …… Equally stable but less stable than I because of charge separation (Both structures have octet on all atoms)(1) …. Correct …… CH4109.280 > NH31070 > H2O1050 > H2S920 (2) …. Correct …… O2+2.50 > O22 > O2−1.5 > O2−21(3) …. Correct …… HF > H2O > NH3 > HClPolarity of H – F > H – O > H – N