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Q.

Which of the following statements is true?

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a

C2H5S⊝is both a stronger base and more nucleophillic than C2H5O⊝

b

C2H5S⊝is a stronger base but is less nucleophilic than C2H5O⊝

c

C2H5S⊝ is a weaker base but is more nucleophilic than C2H5O⊝

d

C2H5S⊝is both a weaker base and less nucleophilic than C2H5O⊝

answer is C.

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Detailed Solution

C2H5S⊝is a weak base than C2H5S⊝but more nucleophilic than C2H5S⊝due to less solvation and more polarizability of donor ‘S’ atom.
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