Q.

Which of the following substituents has +M (Mesomeric) effect?

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a

-CN

b

-CHO

c

-NH3

d

-NO2

answer is C.

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Detailed Solution

+ME groups:  The groups in which the first atom [Which is attached to conjugated system] contains at least one lonepair acts as +ME group.—ME groups: The groups in which the first atom [Which is attached to conjugated system] having (forming) multiple bonds with the electronative atoms like -N, O, S are acting —ME groups, &Condition: The atom should not possess lonepair
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