Q.

For which of the following types of ions is the number of unpaired electrons in octahedral complexes fixed at the same number as in the free ion no matter, how weak or strong the crystal field is?

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a

d3

b

d4

c

d5

d

d6

answer is A.

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Detailed Solution

d3 type of ions- number of unpaired electrons in octahedral complexes is same for weak or strong fieldIigand and in the free ion.
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For which of the following types of ions is the number of unpaired electrons in octahedral complexes fixed at the same number as in the free ion no matter, how weak or strong the crystal field is?