In which of the following will the corrosion of iron be most rapid ?
In pure water
In pure oxygen
In air and moisture
In air and saline water
2Fe+O2+4H+→Fe+2+2H2O;Eo=1.67 V
Moisture in air leads to the formation of H2CO3 or H2SO3 which gives H+ ions that favours corrosion.
Saline water also has low pH value which favours corrosion.