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Q.

Which of the following will give PCl5 ?

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a

PCl5 + dry Cl2 (excess)

b

Red or white phosphorus + dry Cl2 (excess)

c

Phosphorus (white or red) +SO2Cl2

d

All of the above

answer is D.

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Detailed Solution

PCl3+Cl2→ΔPCl5P4+10Cl2→Δ4PCl5P4+10SO2Cl2→Δ4PCl5+10SO2
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