Q.

Which of the following will give(H3PO3 )phosphonic acid on reacting with PCl3 ?

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a

CH3COOH

b

CH3CH2OH

c

HOH

d

All of these

answer is D.

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Detailed Solution

3CH3COOH+PCl3→ 3CH3COCl+H2PO33CH3CH2OH+PCl3→ 3C2H5Cl+H3PO33HOH + PCl3 →  3HCl + H3PO3
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