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Q.

Which of the following will have highest dipole moment?

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a

CH3Br

b

C2H5Br

c

(CH3)2CHBr

d

(CH3)3CBr

answer is D.

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Detailed Solution

As the number of +IE groups increases,the stability of carbo cation increases,the formation of respective carbocation increases,hence the ionisation of C—Br bond increases,i.e., the polarity of C—Br bond increases,hence dipole moment of C—Br bond increases.
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