Which of the following will have highest dipole moment?
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a
CH3Br
b
C2H5Br
c
(CH3)2CHBr
d
(CH3)3CBr
answer is D.
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Detailed Solution
As the number of +IE groups increases,the stability of carbo cation increases,the formation of respective carbocation increases,hence the ionisation of C—Br bond increases,i.e., the polarity of C—Br bond increases,hence dipole moment of C—Br bond increases.