Q.

Which of the following will not be soluble in sodium bicarbonate?

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a

2, 4, 6,-Trinitrophenol

b

Benzoic acid

c

p-Nitrophenol

d

Benzenesulphonic acid

answer is C.

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Detailed Solution

2, 4, 6-Trinitrophenol, benzoic acid and benzenesulphonic acid are more acidic than carbonic acid and hence dissolve in NaHCO3 solution. In contrast, o-nitrophenol is less acidic than carbonic acid and hence does not dissolve in NaHCO3 solution.
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