Which of the following will react faster through SN 1 mechanism?
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a
H2C=CH-CH2Cl
b
C6H5Cl
c
CH2=CHCl
d
CH3CH2Cl
answer is A.
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Detailed Solution
SN1 reaction proceeds through carbocation intermediate. stability of CH2=CH−C+H is maximumC+H2−CH=C H2 ↔ CH2=CH−C+H2CH2 = CH – Cl and C6H5Cl are least reactive as C – Cl bond acquires double bond character due to resonance. C H3−CH2−C l forms C H3−C+H2 which stabilizes through Hyperconjugation and +I effect. stability of CH3C+H2 < CH2 = CH−C+H2