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Q.

Which of the following would be expected to be most highly ionised in water?

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a

CH2ClCH2CH2COOH

b

CH3CHCl.CH2⋅COOH

c

CH3⋅CH2⋅CCl2⋅COOH

d

CH3⋅CH2⋅CHCl.COOH

answer is C.

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Detailed Solution

CH3−CH2−CCl2−COOH; α,α−-dichloro butanoic acid is most acidic. Hence it will easily loose H+ ions in solution.
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Which of the following would be expected to be most highly ionised in water?