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a
LiCl
b
NaCl
c
KCl
d
RbCl
answer is A.
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Detailed Solution
As the size of cation increases , nuclear charge decreasesTherefore nuclear force of attraction on water molecules decreases and hence extent [degree] of hydration decreasesDue to high degree of hydration of Li+ ion, its salts exist as hydrated form i.e., LiCl.2H2O