Q.

Which is low spin complex?

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a

Fe(CN)63−

b

CoNO263−

c

Mn(CN)63−

d

All of these

answer is D.

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Detailed Solution

CN−,NO2−are strong field ligands. Fe(CN)63−    →1 unpaired electron; MM→3BMCoNO263−    →0 unpaired electron; MM→0BMMn(CN)63−    →2 unpaired electrons; MM→8BMAll are low spin complex.
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Which is low spin complex?