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Q.

Which may be added to one litre of water to act a buffer ?

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a

One mole of CH3COOH and one mole of HCl

b

One mole of NH4OH and one mole of NaOH

c

One mole of NH4Cl and one mole of HCl

d

One mole of CH3COOH and 0.5 mole of NaOH

answer is D.

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Detailed Solution

(4)  Acetic acid is weak acid ,it forms salt CH3COONa  with strong base NaOH.Hence it is a acidic buffer.HC2H3O2   +   NaOH    →   C2H3O2Na  +  H2O           1                  0.5                       0                     0            0.5              0                          0.5                0.5   This solution contains weak acid + its salt with strong base and thus acts as acidic buffer.
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