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Q.

Which is the most suitable reagent among the following to distinguish compound (C) from the rest of the compounds ?A CH3C≡CCH3                B CH3CH2-CH2CH3 C CH3CH2C ≡CH             D CH3CH=CH2

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a

Br2 in CCl4

b

Br2 in CH3COOH

c

Alkaline KMnO4

d

Tollen's reagent

answer is D.

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Detailed Solution

Terminal alkynes ≡C - H gives white precipitate with Tollens reagent (ammonical AgNO3)
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