Which one of the following alkyl groups is more powerful electron donating group when they are attached to saturated carbon?

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-CH(CH3)2

- CH(CH3)C2 H5

- CH3

-C(CH3)3

answer is D.

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Detailed Solution

When alkyl group attached to saturated carbon then there is no hyper conjugation effect and only +I-effect operating.As the branching at α-carbon increases electron donating ability by +I-effect increases.

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