Q.

Which one of the following amine is most basic

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a

CH2=CH−NH2

b

CH2=CH−CH2-NH2

c

d

answer is B.

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Detailed Solution

(1), (3), (4) . . . the lone pair of nitrogen is involved in resonance. Lone pair is in conjugation with double bond.Thus they are less basic.(2) . . . Lone pair is localized. It is more basic.
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Which one of the following amine is most basic