Q.
Which one of the following amine is most basic
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a
CH2=CH−NH2
b
CH2=CH−CH2-NH2
c
d
answer is B.
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Detailed Solution
(1), (3), (4) . . . the lone pair of nitrogen is involved in resonance. Lone pair is in conjugation with double bond.Thus they are less basic.(2) . . . Lone pair is localized. It is more basic.
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