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Q.

Which one of the following aqueous solution when subjected to electrolysis using inert electrodes shows change in concentration without any change in composition.

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a

aq.CuCl2

b

aq . K2SO4

c

aq . AgNO3

d

aq.  NaCl

answer is B.

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Detailed Solution

aq.  K2SO4Discharge potential of H2O  is lesser than  K+2H2O +2e−→ H2+2OH−H2  is liberated at cathode.Discharge potential of H2O is lesser than SO4-22H2O →O2+4H++4e-O2 is liberated at anodeLeft over is concentrated. K2SO4 Conc.↑  composition doesn’t change.
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