Which one of the following can give a diazonium salt as final product at 273K-278K when it reacts with nitrous acid
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a
C6H5CH2NH2
b
CH3CH2NH2
c
C6H5NH2
d
All of these
answer is C.
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Detailed Solution
C6H5CH2N+2 and CH3CH2N+2 cannot stabilize through resonane hence they are unstable and immediately hydrolyse to C6H5CH2OH and CH3CH2OH.C6H5N+2 is stable and can stabilize through resonance.