Which one of the following complex exhibits linkage isomerism ?
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a
CrH2O4Cl2Cl
b
CoNH35ONOSO4
c
PtNH34Cl2Br2
d
Cren2Cl2Cl
answer is B.
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Detailed Solution
Complexes containing ambidentate ligands exhibit linkage isomerism.NO2−,ONO−,SCN−,NCS−,CN−,NC− are some important ambidentate ligands. ∴CoNH35ONOSO4 and CoNH35NO2SO4 are linkage isomers.