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Which one of the following complex exhibits linkage isomerism ?

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By Expert Faculty of Sri Chaitanya
a
CrH2O4Cl2Cl
b
CoNH35ONOSO4
c
PtNH34Cl2Br2
d
Cren2Cl2Cl

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detailed solution

Correct option is B

Complexes containing ambidentate ligands exhibit linkage isomerism.NO2−,ONO−,SCN−,NCS−,CN−,NC− are some important ambidentate ligands. ∴CoNH35ONOSO4     and     CoNH35NO2SO4  are linkage isomers.


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The existence of two different coloured complexes with the composition of CoNH34Cl2+ is due to

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