Q.

Which one of the following complex exhibits linkage isomerism ?

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a

CrH2O4Cl2Cl

b

CoNH35ONOSO4

c

PtNH34Cl2Br2

d

Cren2Cl2Cl

answer is B.

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Detailed Solution

Complexes containing ambidentate ligands exhibit linkage isomerism.NO2−,ONO−,SCN−,NCS−,CN−,NC− are some important ambidentate ligands. ∴CoNH35ONOSO4     and     CoNH35NO2SO4  are linkage isomers.
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