Which one of the following complex is paramagnetic with a spin only magnetic moment of 2.82 B.M
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a
MnBr4−2
b
MnCl6−3
c
MnH2O6+2
d
MnCN6−3
answer is D.
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Detailed Solution
(1) and (3) – Mn+23d5 ……. n = 5 …… μ=5.9 BM.... No rearrangementReason –Br- and H2O are weak field ligand.(2) …….. Mn+33d4....n=4...... μ=4.9 BM.... No rearrangementReason – Cl- is a weak field ligand.