Which one of the following compound can undergo C-Cl cleavage most readily to form a stable carbocation
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a
Allyl chloride
b
Vinyl chloride
c
Methyl chloride
d
Ethyl chloride
answer is A.
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Detailed Solution
Stability of CH2=CH-C+H2>CH3-C+H2>C+H3>CH2=C+H; resonance H.C - least stable ; SP2 carbon of vinyl carbocation is electronegative and thus intensifies the positive change, thus least stable