Which one of the following compound gives yellow precipitate when heated with iodine and sodium carbonate
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a
Acetone
b
Diethyl ketone
c
Propionaldehyde
d
Dipheny ketone
answer is A.
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Detailed Solution
Methyl ketones when heated with iodine and sodium carbonate(alkali) give a yellow ppt of iodoform ;This test is also given by ethanol, ethanal and 2-alkanols; 2 - alkanone-CO-CH3→NaOH+I2-COO-+CHI3 ;