Q.

Which one of the following compound gives yellow precipitate when heated with iodine and sodium carbonate

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a

Acetone

b

Diethyl ketone

c

Propionaldehyde

d

Dipheny ketone

answer is A.

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Detailed Solution

Methyl ketones when heated with iodine and sodium carbonate(alkali) give a yellow ppt of iodoform ;This test is also given by ethanol, ethanal and 2-alkanols; 2 - alkanone-CO-CH3→NaOH+I2-COO-+CHI3 ;
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Which one of the following compound gives yellow precipitate when heated with iodine and sodium carbonate