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Which one of the following is a diamagnetic complex ?

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By Expert Faculty of Sri Chaitanya
a
FeCN6−3
b
MnCN6−3
c
NiCN4−2
d
All of these

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detailed solution

Correct option is C

Ni+2 (rearrangement) . . . . In presence of strong ligand like CN- Ni+2 undergoes rearrangement. It is diamagnetic.Option (1)  . . . n = 1Option (2)  . . . n = 2


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Statement 1: The number of unpaired electrons present in CuCl2 complex is zero.

Statement 2: The complex is linear in the solid state with sp-hybridization.

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