Which one of the following is a diamagnetic complex ?
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a
FeCN6−3
b
MnCN6−3
c
NiCN4−2
d
All of these
answer is C.
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Detailed Solution
Ni+2 (rearrangement) . . . . In presence of strong ligand like CN- Ni+2 undergoes rearrangement. It is diamagnetic.Option (1) . . . n = 1Option (2) . . . n = 2