Q.

Which one of the following electrolyte does not liberate oxygen at anode during electrolysis

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a

aq. AgNO3 using inert electrodes

b

Fused NaOH using inert electrodes

c

aq.Na2SO4 using inert electrodes

d

aq. KCl  using inert electrodes

answer is D.

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Detailed Solution

During the electrolysis of aqueous KCl using inert electrodes, chlorine is liberated at anode(explained on the basis of over potential).Anode-2Cl- →Cl2+2e
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