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Q.

Which one of the following electrolytes has the same value of van't Hoff factor (i) as that of Al2SO43 (if all are 100 % ionised)?

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a

AlNO33

b

K4Fe(CN)6

c

K2SO4

d

K3Fe(CN)6

answer is B.

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Detailed Solution

Al2SO43⟶2Al3++3SO42-,i=5 AlNO33⟶Al3++3NO3-,i=4 K4Fe(CN)6⟶4 K++Fe(CN)64-,i=5 K2SO4⟶2 K++SO42-,i=3 K3Fe(CN)6⟶3 K++Fe(CN)63-,i=4
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