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Q.

Which one of the following is expected to exhibit optical isomerism ? (en = ethylenediamine)

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a

Cis−PtNH32Cl2

b

Trans−PtNH32Cl2

c

Cis−Coen2Cl2+

d

Trans−Coen2Cl2+

answer is C.

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Detailed Solution

Optical isomerism is not shown by square planar complexes,Cis−PtNH32Cl2 and Trans−PtNH32Cl2 Octahedral complex, Trans−Coen2Cl2+ does not show optical isomerism (superimposable mirror image). But Cis−Coen2Cl2+ shows optical isomerism

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