Which one of the following is incorrect for ideal solution?
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a
ΔHmix =0
b
ΔUmix=0
c
ΔP=Pobs -Pcalculated by Raoult's law =0
d
ΔGmix =0
answer is D.
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Detailed Solution
For an ideal solution, ΔHmix=0,ΔVmix=0, Now, ΔUmix =ΔHmix -PΔVmix ∴ΔUmix =0 Also,for an ideal solution, pA=xApA°,pB=xBpB°∴ΔP=Pobs -Pcalculated by =0ΔGmix=ΔHmix-TΔSmix For an ideal solution, ΔSmix≠0∴ΔGmix≠0