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Q.

Which one of the following is least reactive towards nucleophilic addition

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a

b

c

d

answer is B.

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Detailed Solution

Aliphatic aldehydes > Aliphatic ketones > Aromatic aldehydes > Aromatic ketones. +I effect and steric hindrance decreases the reactivity by decreasing the electrophilicity of carbonyl carbon. Reactivity∝ 1+I  effect Reactivity∝ 1Steric hindrance
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