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Q.

Which one of the following mixture acts like an acidic buffer

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a

100 ml of 0.1 M HCl + 100 ml 0.1 M NH4OH

b

100 ml of 0.1 M CH3COOH + 50 ml 0.1 M NaOH

c

100 ml of 0.1 M HCl + 100 ml 0.1 M NaOH

d

100 ml of 0.1 M NaOH + 100 ml of 0.1 M NaCl

answer is B.

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Detailed Solution

1  .  .  .HCl10  meq+NH4OH10  meq;It is a salt of strong acid and weak base….not a buffer;2  .  .  . CH3COOH10  meq+NaOH5  meqExcess weak acid and limited strong base…. mixture acts like acidic buffer(3)…salt of strong acid and strong base….not a buffer;(4)…..mixture of strong base and a salt….not a buffer;
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