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Q.

Which one of the following is not correct ?

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a

The central atoms in PF3, ClF3 and XeF2 have sp3d hybridisation

b

The “bond order” of H2, N2 and O2 follows the order : N2 > O2 > H2

c

The ionic nature of KCl, MgCl2 and AlCl3 follows the order KCl > MgCl2 > AlCl3

d

In CsCl lattice, each Cs is surrounded by 8Cl– ions.

answer is A.

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Detailed Solution

⇒ Central atom in PF3 is - sp3 hybridised ,where as central atom in ClF3, XeF2 undergoes sp3d hybridisation.∴ 1st option is incorrect.2)        N2B.O  3     >O22>H21⇒ correctIonic Nature : →KCl >MgCl2 >AlCl3  →K+    Mg+2   Al+3As the positive charge of cation increasespolarising power of cation increases& hence distortion of Cl- anion increases∴ Sharing of electrons increasesHence covalent character increases & ionic character decreases→ Co-ordination number of Cs in CsCl lattice is 8⇒ Correct
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Which one of the following is not correct ?