Q.
Which one of the following not only gives foul smell when heated with chloroform and alcoholic caustic potash but also forms a stable diazonium salt with nitrous acid at 273 K
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a
Benzyl amine
b
N-methyl ethanamine
c
Methanamine
d
Aniline
answer is D.
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Detailed Solution
1-C6H5CH2NH2; 3-CH3NH2 are aliphatic primary amines. They give positive carbyl amine test but cannot give stable diazonium salt;2- CH3-NH-C2H5 is sec. amine;4- primary aryl amine, it gives positive carbyl amine test and gives a stable diazonium salt;
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