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Questions  

Which one of the following pair of complexes represent a pair of ionization isomers?

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By Expert Faculty of Sri Chaitanya
a
CrNH36CoCN6  and  CoNH36CrCN6
b
CoNH33Cl3  and  CrNH34Cl2Cl
c
CoNH34Cl2Br  and  CoNH34ClBrCl
d
PtNH32Cl2  and  PtNH32Br2

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detailed solution

Correct option is C

CoNH34Cl2Br⇌CoNH34Cl2++Br−CoNH34ClBrCl⇌CoNH34ClBr++Cl−These two isomers differ in the ions produced in aqueous solution.


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The existence of two different coloured complexes with the composition of CoNH34Cl2+ is due to

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