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Q.

Which one of the following pair of complexes represent a pair of ionization isomers?

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a

CrNH36CoCN6  and  CoNH36CrCN6

b

CoNH33Cl3  and  CrNH34Cl2Cl

c

CoNH34Cl2Br  and  CoNH34ClBrCl

d

PtNH32Cl2  and  PtNH32Br2

answer is C.

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Detailed Solution

CoNH34Cl2Br⇌CoNH34Cl2++Br−CoNH34ClBrCl⇌CoNH34ClBr++Cl−These two isomers differ in the ions produced in aqueous solution.
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Which one of the following pair of complexes represent a pair of ionization isomers?