Which one of the following pairs of solution is not an acidic buffer?

• A

  ${\mathrm{CH}}_3\mathrm{COOH}\text{ and }{\mathrm{CH}}_3\mathrm{COONa}$

• B

  ${\mathrm{H}}_2{\mathrm{CO}}_3\text{ and }{\mathrm{Na}}_2{\mathrm{CO}}_3$

• C

  ${\mathrm{H}}_3{\mathrm{PO}}_4\text{ and }{\mathrm{Na}}_3{\mathrm{PO}}_4$

• D

  ${\mathrm{HClO}}_4\text{ and }{\mathrm{NaClO}}_4$