First slide

Aplicaitons of VBT

Question

Which of one of the following is a paramagnetic complex

Moderate

A

[Ni(CN)₄]^-2
B

[Ni(CO)₄]
C

[Cr(CN)₆]^-3
D

[Co(en)₃]⁺³

Solution

Cr⁺³(3d³) irrespective of strenth of ligand all “Cr⁺³” octahedral complexes are paramagnetic.

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