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Q.

For which one of the following reaction at equilibrium constant value increases with decrease in temperature.

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a

PCl5(g) ⇌PCl3(g) + Cl2(g) - Q kJ

b

N2g+3H2g⇌2NH3(g)+Q kJ

c

2NH3(g)+Q kJ ⇌N2(g)+3H2(g)

d

2SO3(g)+Q kJ⇌2SO2(g)+O2(g)

answer is B.

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Detailed Solution

For exothermic reaction with decrease in temperature equilibrium constant increases
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For which one of the following reaction at equilibrium constant value increases with decrease in temperature.