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Q.

For which one of the following reaction, the graph  against T is almost horizontal to temperature axis

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a

C(s) + O2(g) →  CO2 (g)

b

2 C(s) + O2 (g)→   2 CO(g)

c

2CO(g) + O2(g)  → 2CO2(g)

d

2Mg(s) + O2(g) →  2MgO(s)

answer is A.

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Detailed Solution

ΔG=ΔH-TΔS ΔH and ΔG almost remain constant with temperature. So ΔG varies with temperature.Case – I: - When ΔS=0, ΔG  is unaffected by ‘T’. Case – II: When ΔS=−ve, ΔG increases with increase in ‘T’Case – III: When ΔS=+ve, ΔG decreases with increase in ‘T’   C(s)+O2(g)→CO2(g) ΔS=0         ΔG is unaffected by temperature.
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For which one of the following reaction, the graph  against T is almost horizontal to temperature axis