For which one of the following reaction, the graph against T is almost horizontal to temperature axis
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a
C(s) + O2(g) → CO2 (g)
b
2 C(s) + O2 (g)→ 2 CO(g)
c
2CO(g) + O2(g) → 2CO2(g)
d
2Mg(s) + O2(g) → 2MgO(s)
answer is A.
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Detailed Solution
ΔG=ΔH-TΔS ΔH and ΔG almost remain constant with temperature. So ΔG varies with temperature.Case – I: - When ΔS=0, ΔG is unaffected by ‘T’. Case – II: When ΔS=−ve, ΔG increases with increase in ‘T’Case – III: When ΔS=+ve, ΔG decreases with increase in ‘T’ C(s)+O2(g)→CO2(g) ΔS=0 ΔG is unaffected by temperature.