Q.

Which one of the following reactions will not form acetaldehyde?

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a

CH2=CH2+O2→H2OPd(II)/Cu(II)

b

CH3CN→ii) H2Oi) DIBAL−H

c

CH3CH2OH→ CrO3−H2SO4

d

CH3CH2OH→573 KCu

answer is C.

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Detailed Solution

CH3−CH2−OH→strong  oxidising agentCrO3.H2SO4  CH3−C||O−OHCH3CH2OH→573KCuCH3−C||O−HCH3CN→2510 KiDiBAL−HCH3−C||O−HCH2=CH2+O2→H2OPdII-CuIICH3−C||O−H
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