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Q.

Which one of the following species cannot exist

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a

SnCl6-2

b

PbF4

c

SiCl6-2

d

PbI2

answer is C.

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Detailed Solution

SiCl6-2 cannot exist because small Si+4 cannot accomodate six large Cl- ions around it. The bond is weak;.
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Which one of the following species cannot exist