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Q.

Which one of the following species is most stable

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a

p−O2N−C6H4−C+H2

b

p−CH3O−C6H4−C+H2

c

p−Cl−C6H4−C+H2

d

C6H5−C+H2

answer is B.

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Detailed Solution

Nitro-group is electron withdrawing therefore decreases stability.Methoxy group is electron releasing. Therefore increases stability by donating electron.Chlorine is also electron withdrawing but its effect is less than −NO2 group.Hence, correct order of stability.
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