Q.

Which one of the following statement is incorrect regarding minimum boiling azeotrope

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a

It shows positive deviations from Raoult's law

b

The two liquids present in the mixture can be separated by fractional distillation

c

∆Hmixing=+Ve

d

∆Vmixing=+Ve

answer is B.

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Detailed Solution

Azeotropic mixture is a constant boiling mixture. At certain concentration, both liquids boil at same temperature.It is not possible to separate them by fractional distillation
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