Which one is the most likely structure of CrCl3. 6H2O ,If 1/3 of total chlorine of the compound is precipitated by adding AgNO3
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a
CrCl3. 6H2O
b
[Cr(H2O)3 Cl3]. (H2O)3
c
[CrCl2 (H2O)4]Cl. 2H2O
d
[CrCl(H2O)5] Cl2.H2O
answer is C.
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Detailed Solution
The ions present in the ionization sphere are precipitated, . Hence [CrCl2(H2O)4]Cl.2H2O contains 1/3 Cl in ionization sphere to be precipitated by AgNO3 as AgCl .