Q.

Which one of them is more volatile component?

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a

CH2Cl2

b

CHCI3

c

Both (a) and (b)

d

Not able to determine

answer is A.

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Detailed Solution

CH2Cl2 is more volatile component than CHCI3 ,pCH2Cl2∘=415mmHg and pCHCl3∘=200mmHg and the vapour phase is also richer in CH2Cl2yCH2Cl2=0.82and yCHCl3=0.18.
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