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Which pair of overlapping can not form covalent bond simultaneously between two atoms ?

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a
If py+py⇒σ-bond, then px+px⇒π-bond
b
If pz+pz⇒σ-bond, then dxy+dxy⇒π-bond
c
If py+py⇒π-bond, then dxz+dxz⇒π-bond
d
If dx2−y2+dx2−y2⇒σ-bond, then dxz+dxz⇒π-bond

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detailed solution

Correct option is B

If pz+pz⟶INA−Zσ-bond dxy+dxy⟶INA−Zδ-bond

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