Q.
For which of the processes is ∆S negative
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a
H2(g)→2H(g)
b
N2(g) 1atm →N2(g)8 atm
c
2SO3(g)→2SO2(g)+O2(g)
d
C(dicmend) →C(qraphite)
answer is C.
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Detailed Solution
The thermodynamic quantity of the system, the decrease in whose value during a process is equal to useful work done by the system i,e., ΔG=ΔH−TΔS, H= enthalpy S= entropy and T= absolute temperature. If an endothermic reaction occurs spontaneously i.e ΔH=+ ve then for reaction to be spontaneous ∆G should be negative that is only possible when ΔS>0 at constant temperature and pressure.
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