Which reaction is not correctly represented for the preparation of alkane ?
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a
b
c
d
CH3I+HI→420KCH4+I2
answer is B.
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Detailed Solution
LiAlH4 convents 3°alkyl halide into alkene thus (2) is incorrect. The reaction is so, because the hydride ion acts as strong base. tertiary carbon is difficult to be attacked ,due to steric effect,hence elimination is favoured. As follows CH33CCl→LiAlH4CH32C=CH2